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Among her other most notable accolades, she was the first Chinese player to win a WTA tour title at the Guangzhou International Women's Open in 2004, the first to reach a Grand Slam singles quarterfinal at the 2006 Wimbledon Championships, and the first to break into the world's top 10.
She also won all of her first seven ITF doubles tournaments she entered.
However, she won her 16th ITF doubles tournament at the same event, the 17th overall doubles title of her career.
That September, she lost in the final of a ,000 tournament to compatriot Zheng Jie, before returning to the WTA circuit, thanks to a wildcard entry into qualifying at the Beijing.
Despite winning the first set, Li lost her first WTA singles match to Anna Zaporozhanova in three sets, but she captured the women's doubles title at Tashkent with Li Ting against Zaporozhanova and Iroda Tulyaganova.
By the end of 2000, Li had won four WTA singles matches, this brought her cumulative ITF singles title count up to 11.After a victory over Ai Sugiyama in the first round at Dubai the following week, it was Schnyder once again who stopped her from reaching the later stages of the event.